Pollutant emissions in common-rail diesel engines in extraurban cycle: rapeseed oils vs diesel fuel

The new energy strategy of EU (i.e., Directive 2009/28/EC) requires increasing the use of biofuels in transports up to at least 10% of the total fuel consumption. In the last years, the share of Diesel engines in automotive applications reached about 55% in EU market, thus trying to widen the alternatives to Diesel fuel is very important. In this framework straight vegetable oils (SVO) can represent one of the available possibilities at least in some specific applications (i.e., public transportation, hybrid or marine propulsion, etc.). SVO properties may be very different form Diesel fuel, thus operating a Diesel engine with SVO might result in some problems, especially in automotive configuration where the electronic unit acts as if it is working with Diesel fuel. This reflects in possible engine power and torque reduction, maintenance problems, and pollutant emissions during vehicles running. The latter aspect is the focus of the present paper. In this work, we used a turbocharged, four stroke, four cylinders, water cooled, commonrail multijet Diesel engine in automotive configuration to simulate the extraurban cycle according to the EU standard, comparing pollutant emissions in case of SVO and gasoil fuelling

Unconventional Hall effect in pnictides from interband interactions

We calculate the Hall transport in a multiband systems with a dominant interband interaction between carriers having electron and hole character. We show that this situation gives rise to an unconventional scenario, beyond the Boltzmann theory, where the quasiparticle currents dressed by vertex corrections acquire the character of the majority carriers. This leads to a larger (positive or negative) Hall coefficient than what expected on the basis of the carrier balance, with a marked temperature dependence. Our results explain the puzzling measurements in pnictides and they provide a more general framework for transport properties in multiband materials.Comment: 5 pages, 2 figure

Nematicity at the Hund's metal crossover in iron superconductors

The theoretical understanding of the nematic state of iron-based superconductors and especially of FeSe is still a puzzling problem. Although a number of experiments call for a prominent role of local correlations and place iron superconductors at the entrance of a Hund's metal state, the effect of the electronic correlations on the nematic state has been theoretically poorly investigated. In this work we study the nematic phase of iron superconductors accounting for local correlations, including the effect of the Hund's coupling. We show that Hund's physics strongly affects the nematic properties of the system. It severely constrains the precise nature of the feasible orbital-ordered state and induces a differentiation in the effective masses of the zx/yz orbitals in the nematic phase. The latter effect leads to distinctive signatures in different experimental probes overlooked so far in the interpretation of experiments. As notable examples the splittings between zx and yz bands at \u393 and M points are modified, with important consequences for angle-resolved photoemission spectroscopy measurements

Remarkable low-energy properties of the pseudogapped semimetal Be5Pt

We report measurements and calculations on the properties of the intermetallic compound Be5Pt. High-quality polycrystalline samples show a nearly constant temperature dependence of the electrical resistivity over a wide temperature range. On the other hand, relativistic electronic structure calculations indicate the existence of a narrow pseudogap in the density of states arising from accidental approximate Dirac cones extremely close to the Fermi level. A small true gap of order 3c3 meV is present at the Fermi level, yet the measured resistivity is nearly constant from low to room temperature. We argue that this unexpected behavior can be understood by a cancellation of the energy dependence of density of states and relaxation time due to disorder, and discuss a model for electronic transport. With applied pressure, the resistivity becomes semiconducting, consistent with theoretical calculations that show that the bandgap increases with applied pressure. We further discuss the role of Be inclusions in the samples

New national and regional Annex I Habitat records: From #37 to #44

In this contribution, Italian new data concerning the distribution of the Annex I Habitats 3150, 3170*, 3260, 4090, 91L0, 91M0, 9340 are reported. In detail, 20 new occurrences in Natura 2000 sites are presented and 30 new cells are added in the EEA 10 km × 10 km reference grid. The new data refer to the Italian administrative regions of Campania, Lazio, Sardinia, Sicily, Tuscany, and Umbria

Italian Vascular Flora: New Findings, Updates and Exploration of Floristic Similarities between Regions

The tradition of floristic studies in Italy has made it possible to obtain a good knowledge of plant diversity both on a national and regional scale. However, the lack of knowledge for some areas, advances in plant systematics and human activities related to globalization, highlight the need for further studies aimed at improving floristic knowledge. In this paper, based on fieldwork and herbaria and literature surveys, we update the knowledge on the Italian vascular flora and analyze the floristic similarities between the administrative regions. Four taxa, all exotic, were recorded for the first time in Italy and Europe. In detail, Elaeodendron croceum, Kalanchoë blossfeldiana, and Sedum spathulifolium var. spathulifolium were found as casual aliens, while Oxalis brasiliensis was reported as historical record based on some herbarium specimens. Furthermore, Kalanchoë laxiflora was confirmed as a casual alien species for Italy and Europe. Status changes for some taxa were proposed at both national and regional levels, as well as many taxa were reported as new or confirmed at the regional level. Currently the Italian vascular flora comprises 9150 taxa of which 7547 are native (of which 1598 are Italian endemics) and 1603 are exotic at the national level. The multivariate analysis of updated floristic data on a regional scale showed a clear distribution along the latitudinal gradient, in accordance with the natural geographical location of the regions in Italy. This pattern of plants distribution was not affected by the introduction of alien species. Despite some taxonomic and methodological issues which are still open, the data obtained confirm the important role of floristic investigations in the field and in herbaria, as well as the collaborative approach among botanists, in order to improve the knowledge of the Italian and European vascular flora

High-pressure study of the low- Z rich superconductor Be22Re

With Tc 3c9.6K, Be22Re exhibits one of the highest critical temperatures among Be-rich compounds. We have carried out a series of high-pressure electrical resistivity measurements on this compound to 30 GPa. The data show that the critical temperature Tc is suppressed gradually at a rate of dTc/dP=-0.05K/GPa. Using density functional theory (DFT) calculations of the electronic and phonon density of states (DOS) and the measured critical temperature, we estimate that the rapid increase in lattice stiffening in Be22Re overwhelms a moderate increase in the electron-ion interaction with pressure, resulting in the decrease in Tc. High-pressure x-ray diffraction measurements show that the ambient pressure crystal structure of Be22Re persists to at least 154 GPa